Nitrogen in the Environment: How Nitrogen Enters Groundwater
Scott C. Killpack and Daryl Buchholz
Department of Agronomy
Nitrogen can be found in many different organic and inorganic forms in our environment. The air we breathe is composed of 78 percent nitrogen. Nitrogen can also be found in many varied forms in the soil. Plants need nitrogen from the soil for proper growth and development but are only able to use very specific forms of nitrogen. Plants cannot use the form of nitrogen found in the atmosphere.
Natural biological process carried out by microorganisms in the soil convert organic nitrogen to inorganic forms, which plants are able to use. Organic nitrogen is a common component in plant residues and organic matter. Ultimately, organic nitrogen is converted to inorganic ammonium (NH-). Nitrate is the form of nitrogen that is most used by plants for growth and development. Where crops are grown, nitrates can also emanate from nitrogen fertilizers and manure. Nitrate, regardless of its source, is the form of nitrogen that can get into groundwater.
Unlike ammonium, nitrate does not attach to soil particles and, as a result, is easily moved by water. How nitrates move with water in the soil can be best illustrated by what takes place when soils become wet from rainfall. When rainfall takes place, the soil becomes wet and the air spaces between soil particles begin to fill with water. If rainfall is heavy enough, the air spaces become filled to a point that forces of gravity will cause water to move downward in the soil.
As water moves downward, nitrates will also be carried downward with water. The downward movement of nitrates in the soil is referred to as leaching.
What affects the degree of nitrate leaching?
How much water a soil can hold strongly influences how much leaching will take place. For example, by their nature sandy soils cannot hold as much water as clay soils. This means that leaching of nitrates will take place much more easily in a sandy soil compared to a clay soil. Often, leaching is not a significant factor in heavy clay soils.
Other factors that can affect nitrate leaching include amount of rainfall, amount of water use by plants, and how much nitrate (NO-) is present in the soil system.
Whether nitrates continue to leach downward, and into groundwater, depends on underlying soil and/or bedrock conditions, as well as depth to groundwater. If depth to groundwater is shallow and the underlying soil is sandy, the potential for nitrates to enter groundwater is relatively high. However, if depth to groundwater is deep and the underlying soil is heavy clay, nitrates will not likely enter groundwater. In some cases where dense hardpans are present, nitrate leaching will not progress beyond the depth of the hardpan.
The potential of nitrates from animal manure and nitrogen fertilizers getting into groundwater can be reduced through good management practices. Applying manure and nitrogen fertilizers when crops are actively growing and using nitrates for growth and development will reduce the amount of nitrate in the soil system and thus the amount that could potentially be leached. However, little can be done to minimize the leaching of nitrates into groundwater that result from the ongoing decay of organic matter in the soil. In this situation, nitrates are simply a natural biological result of an ongoing cycle of nitrogen transformation processes in the soil.